Nobody knows more about flavor than professional chefs; guest judge Robert Irvine presides over a pressure cooker of competition as three experienced chefs battle to turn raw ingredients into high-proof, culinary-class spirits.

Moonshiners stars Richard Landry, Killer Beaz and Howard Thompson compete to turn spicy peppers into tasty, high-proof moonshine. But it takes a master moonshiner to run a balanced hot liquor, and every misstep comes at the price of sweat and tears.

Ever since Josh Owens' footage went viral showing a moonshiner in Brazil making liquor from sugar cane juice in just two days, Josh couldn't wait to judge a competition in which three top distillers competed to make cachaça, Brazil's national spirit.

Mark, Digger and Tim judge as three top distillers go head-to-head to distill off-the-shelf beers into high-proof liquor. Only the distiller who can produce the best-tasting beer-shine will be crowned Master Distiller.

Tickle's mom brings the cake as three top distillers compete to turn a bakery's worth of cookies and confections into scrumptious, high-proof liquor. Judged by Mark, Digger, Tim and guest judge Millie Peartree, only one will be named Master Distiller.