Key begins to fixate upon the idea of becoming a pop idol herself as the surest way to making 30,000 friends. In the meantime, Ajo's team are trying to determine whether she might be where Dr. Mima cached his last technological secrets before dying. When Key's presence (care of Shuichi) disrupts Miho Utsuse's latest concert, the company sends out two PPORs to hunt Key down, remotely controlled by a dangerous operative known only as 'D'.

Prince Snake-Eye convinces Key to come to his temple. The child of two of his followers is deathly ill, but their faith precludes medical intervention... so he hopes that Key can cure the boy with her 'supernatural' powers. However, Ajo's lead soldier 'D' has finally tracked Key down, and a confrontation between him, Tomoyo, and Prince Snake-Eye ensues.

Everyone's fave arch-henchman 'D' is still convalescing from his battle at the end of the previous DVD, Awakening (Volume 1), but Ajo – not being what you'd call a kind-hearted employer – leaves him locked in a cell with only a computer terminal and the mission of 'finding out what went wrong with the PPORs'. No wonder 'D' is having nightmares... about Key? Meanwhile in Gotham City, things start to look up for Sakura and Key as Shuichi comes through with his connections and Tsurugi himself phones to set up a meeting. But nothing can be taken for granted when you have Prince Snake-Eye tapping your phone...